As discussed in other articles alignment is very important in resistance welding. It dictates force and current application/distribution and prevents distortion of the workpiece. If not set up properly the part can be distorted and/or the electrode face can have exceedingly high current densities. This can result in distorted parts, expulsion and excessive electrode face wear.

In many shops alignment is done by eyeball?
A better method is a ruler.
Carbon paper has been a good choice for a long time.
Laser lights on the holders is the newest option for alignment.
For additional Information in this blog:
WHAT IS A GOOD WAY TO ALIGN THE TOP AND BOTTOM RESISTANCE WELDING ELECTRODE?
References: RWMA -Resistance Welding Manual 4th Edition